Preparation and structural-bonding characterization of a 50-electron trianglular cobalt cluster, [Co(C5H4CO2Me)]3(S)(NtBu), with triply bridging sulfido and imido ligands: singlet-triplet equilibrium in solid and solution states

• Published in: Inorganic chemistry Vol. 27; no. 17; pp. 2958 - 2963
• Main Authors: WAKATSUKI, Y, OKADA, T, YAMAZAKI, H, GUOBAO CHENG
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 1988
• Subjects: Atomic and molecular physics; Exact sciences and technology; Interatomic distances and angles; Molecular properties and interactions with photons; Physics; Properties of molecules and molecular ions; Cobalt Complexes; Thio complex; Chemical solution; Temperature; Trinuclear complex; Orbital interaction; Theoretical study; Transition metal Complexes; Experimental study; Inorganic compound; Magnetic susceptibility; Mu complex; Least squares method; Preparation; Extended Hueckel method; NMR spectrum; Conformation; Crystalline structure
• ISSN: 0020-1669; 1520-510X