α,β-Unsaturated Diazoketones as Platforms in the Asymmetric Synthesis of Hydroxylated Alkaloids. Total Synthesis of 1-Deoxy-8,8a-diepicastanospermine and 1,6-Dideoxyepicastanospermine and Formal Synthesis of Pumiliotoxin 251 D

• Published in: Journal of organic chemistry Vol. 77; no. 21; pp. 9926 - 9931
• Main Authors: BERNARDIM, Barbara, PINHO, Vagner D, BURTOLOSO, Antonio C. B
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 2012
• Subjects: Chemistry; Exact sciences and technology; Heterocyclic compounds; Heterocyclic compounds with only one n hetero atom and condensed derivatives; Organic chemistry; Preparations and properties; Hydroxylation; Nitrogen heterocycle; Dihydroxylation; Total synthesis; Unsaturated compound; Stereoselectivity; Diazoketone; Alkaloid; Asymmetric synthesis; Wolff rearrangement; Indolizidine derivative; Epoxidation; Chemical synthesis
• ISSN: 0022-3263; 1520-6904