Chiral photochemistry in a confined space: torquoselective photoelectro-cyclization of pyridones within an achiral hydrophobic capsule

• Published in: Tetrahedron Vol. 65; no. 35
• Main Authors: KUMAR SUNDARESAN, Arun, GIBB, Corinne L. D, GIBB, Bruce C, RAMAMURTHY, V
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier 2009
• Subjects: Chemistry; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; General and physical chemistry; Heterocyclic compounds; Heterocyclic compounds with only one n hetero atom and condensed derivatives; Kinetics and mechanisms; Materials science; Methods of nanofabrication; Organic chemistry; Photochemistry; Physical chemistry of induced reactions (with radiations, particles and ultrasonics); Physics; Preparations and properties; Reactivity and mechanisms; Supramolecular and biochemical assembly; Correlation; Molecular structure; Nitrogen heterocycle; Chiral compound; NMR spectrometry; Selectivity; Photochemical reaction; Pyridine derivatives; Hydrogen 1; Chiral auxiliary; Molecular assembly; Supramolecular structure; Reaction mechanism; Photochemistry; Chemical solution; Pyridone derivatives; Chiral photochemistry; Electrocyclic reaction; Pyridones; Hydrophobic compound; Host-guest; Diastereoselectivity; Confined space; Electrocyclization; Solid state; Cyclization; Acetonitrile; Inclusion compound; Supramolecular assemblies; Conformation
• ISSN: 0040-4020; 1464-5416