sup 31 P and sup 195 Pt NMR data of several T-frame diplatinum complexes that exhibit unusual structure, bonding, and reactivity

The authors have previously reported the synthesis, structure, and bonding of several new dinuclear complexes including seven diplatinum complexes. The analysis of the {sup 31}P and {sup 195}Pt NMR spectra of these complexes is presented herein. These data have considerable diagnostic values for det...

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Bibliographic Details
Published inInorganic chemistry Vol. 29:15
Main Authors Baralt, E., Lukehart, C.M.
Format Journal Article
LanguageEnglish
Published United States 25.07.1990
Subjects
400201 - Chemical & Physicochemical Properties
400202 - Isotope Effects, Isotope Exchange, & Isotope Separation
AROMATICS
COMPLEXES
DATA
DAYS LIVING RADIOISOTOPES
ELECTRONIC STRUCTURE
EVEN-ODD NUCLEI
EXPERIMENTAL DATA
HALOGEN COMPOUNDS
HEAVY NUCLEI
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
INTERNAL CONVERSION RADIOISOTOPES
ISOMERIC TRANSITION ISOTOPES
ISOTOPES
LIGHT NUCLEI
NMR SPECTRA
NUCLEI
NUMERICAL DATA
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
PHOSPHORUS 31
PHOSPHORUS ISOTOPES
PLATINUM 195
PLATINUM COMPLEXES
PLATINUM ISOTOPES
RADIOISOTOPES
SPECTRA
STABLE ISOTOPES
TRANSITION ELEMENT COMPLEXES
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Summary:The authors have previously reported the synthesis, structure, and bonding of several new dinuclear complexes including seven diplatinum complexes. The analysis of the {sup 31}P and {sup 195}Pt NMR spectra of these complexes is presented herein. These data have considerable diagnostic values for determining the formation of diplatinum complexes of this structural type and may lead to a better understanding of the usual electronic structure of these molecules. 12 refs., 1 tab.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic00340a030