Preparation and characterization of mesoporous N-doped and sulfuric acid treated anatase TiO{sub 2} catalysts and their photocatalytic activity under UV and Vis illumination

• Published in: Journal of solid state chemistry Vol. 182; no. 11
• Main Authors: Kun, Robert, Tarjan, Sandor, Oszko, Albert, Seemann, Torben, Zoellmer, Volker, Busse, Matthias, Dekany, Imre, Department of Colloid Chemistry, University of Szeged, Aradi vt. 1, H-6720 Szeged
• Format: Journal Article
• Language: English
• Published: United States 15.11.2009
• Subjects: ABSORPTION; ADSORPTION; AROMATICS; BOSONS; CATALYSIS; CATALYSTS; CHALCOGENIDES; COHERENT SCATTERING; DIFFRACTION; DOPED MATERIALS; ELECTROMAGNETIC RADIATION; ELECTRON SPECTROSCOPY; ELEMENTARY PARTICLES; ELEMENTS; HYDROGEN COMPOUNDS; HYDROXY COMPOUNDS; ILLUMINANCE; INORGANIC ACIDS; INORGANIC COMPOUNDS; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; MASSLESS PARTICLES; MATERIALS; NANOSTRUCTURES; NITROGEN; NONMETALS; OPTICAL PROPERTIES; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; PHENOL; PHENOLS; PHOTOCATALYSIS; PHOTOELECTRON SPECTROSCOPY; PHOTONS; PHYSICAL PROPERTIES; RADIATIONS; SCATTERING; SORPTION; SPECTROSCOPY; SULFUR COMPOUNDS; SULFURIC ACID; SURFACE TREATMENTS; TEMPERATURE RANGE; TEMPERATURE RANGE 0400-1000 K; TITANIUM COMPOUNDS; TITANIUM OXIDES; TRANSITION ELEMENT COMPOUNDS; VISIBLE RADIATION; X-RAY DIFFRACTION; X-RAY PHOTOELECTRON SPECTROSCOPY
• ISSN: 0022-4596; 1095-726X
• DOI: 10.1016/j.jssc.2009.08.022

Nitrogen-doped TiO{sub 2} catalysts were prepared by a precipitation method. The samples were calcined at 400 deg. C for 4 h in air. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), low temperature N{sub 2}-adsorption was used for structural characterization and UV-diffuse reflectance (UV-DR) was applied to investigate the optical properties of the as-prepared samples. It was found that microporous N-doped catalysts have solely anatase crystalline structure. Acidic treatment of the calcined samples was performed using sulfuric acid agitation. The crystalline structure remained unchanged due to surface treatment, while the porosity and the surface areas (a{sub BET}{sup S}) were decreased dramatically. Optical characterization of the doped catalysts showed that they could be excited by visible light photons in the 400-500 nm wavelength range (lambda{sub g,1}={approx}390 nm, lambda{sub g,2}={approx}510 nm). It was also established that surface treatment enhances the Vis-light absorption of the N-TiO{sub 2} powders. Finally the catalysts were tested in the photocatalytic degradation of phenol in aqueous suspensions. Two different light sources were used; one of them was a UV-rich high pressure Hg-lamp, while the other was a tubular visible light source. We found that using visible light illumination N-doped, acid treated TiO{sub 2} samples were more catalytically active than non-doped TiO{sub 2} catalysts. - Graphical abstract: The effect of the acid treatment on the visible-light-driven photocatalytic activity of the N-doped, anatase TiO{sub 2} catalysts.