Defect behavior and radiation tolerance of MAB phases (MoAlB and Fe2AlB2) with comparison to MAX phases

• Published in: Acta materialia Vol. 196; no. C
• Main Authors: Zhang, Hongliang, Kim, Jun Young, Su, Ranran, Richardson, Peter, Xi, Jianqi, Kisi, Erich, O'Connor, John, Shi, Liqun, Szlufarska, Izabela
• Format: Journal Article
• Language: English
• Published: United States Elsevier 01.09.2020
• Subjects: Defects; DFT; MAB phases; MATERIALS SCIENCE; MAX phases; Metallurgy & Metallurgical Engineering; Radiation; TEM
• ISSN: 1359-6454; 1873-2453

MAB phases are a new class of layered ternary materials that have already shown a number of outstanding properties. Here, we investigate defect evolution and radiation tolerance of two MAB phases, MoAlB and Fe2AlB2, using a combination of experimental characterization and first-principles calculations. We find that Fe2AlB2 is more tolerant to radiation-induced amorphization than MoAlB, both at 150 °C and at 300 °C. The results can be explained by the fact that the Mo Frenkel pair is unstable in MoAlB and as a result, irradiated MoAlB is expected to have a significant concentration of MoAl antisites, which are difficult to anneal even at 300 °C. We find that the tolerance to radiation-induced amorphization of MAB phases is lower than in MAX phases, but it is comparable to that of SiC. However, MAB phases do not show radiation-induced cracking which is observed in MAX phases under the same irradiation conditions. This research suggests that MAB phases might be a promising class of materials for applications that involve radiation.