Fe Oxides on Ag Surfaces: Structure and Reactivity

• Published in: Topics in catalysis Vol. 60; no. 6-7
• Main Authors: Shipilin, M., Lundgren, E., Gustafson, J., Zhang, C., Bertram, F., Nicklin, C., Heard, C. J., Gronbeck, H., Zhang, F., Choi, J., Mehar, V., Weaver, J. F., Merte, L. R.
• Format: Journal Article
• Language: English
• Published: United States Springer 09.09.2016
• Subjects: CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; FeO; INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; MATERIALS SCIENCE; Reactivity; Single crystal surfaces; Surface structure; Surface X-ray diffraction
• ISSN: 1022-5528; 1572-9028

One layer thick iron oxide films are attractive from both applied and fundamental science perspectives. The structural and chemical properties of these systems can be tuned by changing the substrate, making them promising materials for heterogeneous catalysis. In the present work, we investigate the structure of FeO(111) monolayer films grown on Ag(100) and Ag(111) substrates by means of microscopy and diffraction techniques and compare it with the structure of FeO(111) grown on other substrates reported in literature. We also study the NO adsorption properties of FeO(111)/Ag(100) and FeO(111)/Ag(111) systems utilizing different spectroscopic techniques. Finally, we discuss similarities and differences in the data obtained from adsorption experiments and compare it with previous results for FeO(111)/Pt(111).