Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii )

Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.

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Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 27
Main Authors Das, Atanu K., Engelhard, Mark H., Lense, Sheri, Roberts, John A. S., Bullock, R. Morris
Format Journal Article
LanguageEnglish
Published United States Royal Society of Chemistry 01.01.2015
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Abstract Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.
AbstractList Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.
Author Roberts, John A. S.
Bullock, R. Morris
Lense, Sheri
Das, Atanu K.
Engelhard, Mark H.
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  fullname: Das, Atanu K.
  organization: Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland; USA
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  fullname: Engelhard, Mark H.
  organization: Environmental Molecular Sciences Laboratory; Pacific Northwest National Laboratory; Richland; USA
– sequence: 3
  fullname: Lense, Sheri
  organization: Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland; USA
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  fullname: Roberts, John A. S.
  organization: Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland; USA
– sequence: 5
  fullname: Bullock, R. Morris
  organization: Center for Molecular Electrocatalysis; Physical Sciences Division; Pacific Northwest National Laboratory; Richland; USA
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Snippet Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction,...
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SubjectTerms catalysis (homogeneous), catalysis (heterogeneous), solar (fuels), bio-inspired, energy storage (including batteries and capacitors), hydrogen and fuel cells, charge transport, materials and chemistry by design, synthesis (novel materials)
Title Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii )
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