Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni( ii )

Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.

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Bibliographic Details
Published inDalton transactions : an international journal of inorganic chemistry Vol. 44; no. 27
Main Authors Das, Atanu K., Engelhard, Mark H., Lense, Sheri, Roberts, John A. S., Bullock, R. Morris
Format Journal Article
LanguageEnglish
Published United States Royal Society of Chemistry 01.01.2015
Subjects
catalysis (homogeneous), catalysis (heterogeneous), solar (fuels), bio-inspired, energy storage (including batteries and capacitors), hydrogen and fuel cells, charge transport, materials and chemistry by design, synthesis (novel materials)
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Summary:Covalent tethering of a P2N2ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a CuI-catalyzed “click” reaction, followed by metallation with NiII.
Bibliography:USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
AC05-76RL01830
ISSN:1477-9226
1477-9234
DOI:10.1039/C5DT00162E