Synthesis and Electrochemical Properties of Li3V2(PO4)3-LiMnPO4 Composite Cathode Material for Lithium-ion Batteries

• Published in: Bulletin of the Korean Chemical Society pp. 433 - 436
• Main Authors: 윤진식, Soo Kim, 조병원, 이관영, 정경윤, 장원영
• Format: Journal Article
• Language: English
• Published: 대한화학회 01.02.2013
• Subjects: 화학
• ISSN: 0253-2964; 1229-5949

Carbon-coated Li3V2(PO4)3-LiMnPO4 composite cathode materials are first reported in this work, prepared by the mechanochemical process with a complex metal oxide as the precursor and sucrose as the carbon source. X-ray diffraction pattern of the composite material indicates that both olivine LiMnPO4 and monoclinic Li3V2(PO4)3 co-exist. We further investigated the electrochemical properties of our Li3V2(PO4)3-LiMnPO4 composite cathode materials using galvanostatic charging/discharging tests, where our Li3V2(PO4)3-LiMnPO4 composite electrode materials exhibit the charge/discharge efficiency of 91.9%, while Li3V2(PO4)3 and LiMnPO4 exhibit the efficiency of 87.7 and 86.7% in the first cycle. The composites display unique electrochemical performances in terms of overvoltage and cycle stability, displaying a reduced gap of 141.6 mV between charge and discharge voltage and 95.0% capacity efficiency after 15th cycles. KCI Citation Count: 7