Substituent effects in the hydrogenation of Δ1,9-octalins
The presence of the 4α-methyl group in olefin 4 or in conjugated ketone 10 prevents catalytic hydrogenation from the α side, leading exclusively to cis-fused decalins.
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| Published in | Canadian journal of chemistry Vol. 62; no. 2; pp. 273 - 276 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Ottawa, Canada
NRC Research Press
01.02.1984
|
| Online Access | Get full text |
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| Abstract | The presence of the 4α-methyl group in olefin
4
or in conjugated ketone
10
prevents catalytic hydrogenation from the α side, leading exclusively to cis-fused decalins. |
|---|---|
| AbstractList | The presence of the 4α-methyl group in olefin
4
or in conjugated ketone
10
prevents catalytic hydrogenation from the α side, leading exclusively to cis-fused decalins. |
| Abstract_FL | On rapporte que l'hydrogénation catalytique de l'oléfine
4
ou de la cétone conjuguée
10
conduit exclusivement a la cis-décaline correspondante étant donné la présence du groupement méthyle-4α qui empêche la réaction de s'effectuer du côté α de la molécule. [Traduit par le journal] |
| Author | Breining, Tibor Schmidt, Cirill |
| Author_xml | – sequence: 1 givenname: Cirill surname: Schmidt fullname: Schmidt, Cirill – sequence: 2 givenname: Tibor surname: Breining fullname: Breining, Tibor |
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| ContentType | Journal Article |
| DOI | 10.1139/v84-045 |
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| Discipline | Chemistry |
| EISSN | 1480-3291 |
| EndPage | 276 |
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| PublicationTitle | Canadian journal of chemistry |
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| PublicationYear | 1984 |
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| Snippet | The presence of the 4α-methyl group in olefin
4
or in conjugated ketone
10
prevents catalytic hydrogenation from the α side, leading exclusively to cis-fused... |
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| StartPage | 273 |
| Title | Substituent effects in the hydrogenation of Δ1,9-octalins |
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