Substituent effects in the hydrogenation of Δ1,9-octalins
The presence of the 4α-methyl group in olefin 4 or in conjugated ketone 10 prevents catalytic hydrogenation from the α side, leading exclusively to cis-fused decalins.
Saved in:
| Published in | Canadian journal of chemistry Vol. 62; no. 2; pp. 273 - 276 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Ottawa, Canada
NRC Research Press
01.02.1984
|
| Online Access | Get full text |
Cover
Loading…
| Summary: | The presence of the 4α-methyl group in olefin
4
or in conjugated ketone
10
prevents catalytic hydrogenation from the α side, leading exclusively to cis-fused decalins. |
|---|---|
| ISSN: | 0008-4042 1480-3291 |
| DOI: | 10.1139/v84-045 |