Synthesis of Neopentyl Biphenylsulfonates Using the Suzuki-Miyaura Reaction

Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorob...

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Bibliographic Details
Published inBulletin of the Korean Chemical Society Vol. 24; no. 11; pp. 1632 - 1636
Main Authors Cho, Chul-Hee, Kim, Chul-Bae, Sun, Myung-Chul, Park, Kwang-Yong
Format Journal Article
LanguageKorean
Published 2003
Subjects
Cross-coupling
Biphenylsulfonates
Arylboronic acid
Bromobenzenesulfonates
Suzuki-Miyaura reaction
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Summary:Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.
Bibliography:KISTI1.1003/JNL.JAKO200302727012410
ISSN:0253-2964
1229-5949