High-resolution stimulated Raman spectroscopy and analysis of the nu2, nu5 and 2 nu6 bands of 34SF6
The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahe...
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| Published in | Molecular physics Vol. 104; pp. 2653 - 2661 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Taylor & Francis
2006
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| Subjects | |
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| Abstract | The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahedral XY6 molecules. We also present a preliminary analysis of the 2nu6 band for both 32SF6 and 34SF6. Finally, we give the S-32 - S-34 isotopic shifts for all the SF6 fundamentals. |
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| AbstractList | The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahedral XY6 molecules. We also present a preliminary analysis of the 2nu6 band for both 32SF6 and 34SF6. Finally, we give the S-32 - S-34 isotopic shifts for all the SF6 fundamentals. |
| Author | Boudon, Vincent Willner, Helge Ramos, A. Domenech, J.L. Bermejo, Dionisio |
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| Keywords | NON-CO2 GREENHOUSE GASES SF6 EMISSIONS COMBINATION BAND SPECTRUM NU BAND MOLECULES REGION |
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| Snippet | The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of... |
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| Title | High-resolution stimulated Raman spectroscopy and analysis of the nu2, nu5 and 2 nu6 bands of 34SF6 |
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