High-resolution stimulated Raman spectroscopy and analysis of the nu2, nu5 and 2 nu6 bands of 34SF6

The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahe...

Full description

Saved in:
Bibliographic Details
Published inMolecular physics Vol. 104; pp. 2653 - 2661
Main Authors Boudon, Vincent, Domenech, J.L., Ramos, A., Bermejo, Dionisio, Willner, Helge
Format Journal Article
LanguageEnglish
Published Taylor & Francis 2006
Subjects
Online AccessGet full text

Cover

Loading…
More Information
Summary:The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahedral XY6 molecules. We also present a preliminary analysis of the 2nu6 band for both 32SF6 and 34SF6. Finally, we give the S-32 - S-34 isotopic shifts for all the SF6 fundamentals.
ISSN:0026-8976
1362-3028
DOI:10.1080/00268970600722921