High-resolution stimulated Raman spectroscopy and analysis of the nu2, nu5 and 2 nu6 bands of 34SF6
The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahe...
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Published in | Molecular physics Vol. 104; pp. 2653 - 2661 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Taylor & Francis
2006
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Subjects | |
Online Access | Get full text |
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Summary: | The nu2, nu5 and 2nu6 regions of 24SF6 have been studied by stimulated Raman spectroscopy. We used an isotopically pure sample of 34SF6. A detailed analysis of the nu2 and nu5 fundamentals has been performed with the HTDS program suite (icb.u-bourgogne.fr/OMR/SMA/SHTDS/HTDS.html) dedicated to octahedral XY6 molecules. We also present a preliminary analysis of the 2nu6 band for both 32SF6 and 34SF6. Finally, we give the S-32 - S-34 isotopic shifts for all the SF6 fundamentals. |
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ISSN: | 0026-8976 1362-3028 |
DOI: | 10.1080/00268970600722921 |