Hetero-Diels-Alder reaction of nitrosoalkenes with 2H-pyrrole: experimental and theoretical approach

Hetero-Diels–Alder reactions opposing 2H-pyrroles to substituted nitrosoalkenes are described. The chemoselectivity and regiospecificity of the reaction are discussed. New fused pyrrolo-[1,5-e]-1,2,4a-oxadiazines and pyrrolo-[1,5-d]-imidazoles-1-oxide structures are reported.

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Bibliographic Details
Published inTetrahedron Vol. 58; pp. 1507 - 1512
Main Authors Tahdi, A., Lafquih Titouani, S., Soufiaoui, M., Komiha, N., Kabbaj, O., Hegazi, S., Mazzah, A., Eddaif, A.
Format Journal Article
LanguageFrench
Published Elsevier 2002
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Summary:Hetero-Diels–Alder reactions opposing 2H-pyrroles to substituted nitrosoalkenes are described. The chemoselectivity and regiospecificity of the reaction are discussed. New fused pyrrolo-[1,5-e]-1,2,4a-oxadiazines and pyrrolo-[1,5-d]-imidazoles-1-oxide structures are reported.
ISSN:0040-4020
DOI:10.1016/S0040-4020(01)01199-1