In Situ Synthesis of Crystalline MoS[sub.2]@ZIF-67 Nanocomposite for the Efficient Removal of Methyl Orange Dye from Aqueous Media

• Published in: Micromachines (Basel) Vol. 14; no. 8
• Main Authors: Nawz, Tahreem Haq, Masood, Muhammad Talha, Safdar, Amna, Shahid, Muhammad, Noor, Tayyaba, Hussain, Muzammil, Razi, Ayesha, Umer, Malik Adeel
• Format: Journal Article
• Language: English
• Published: MDPI AG 01.07.2023
• Subjects: Azo compounds; Organic dyes; Germany
• ISSN: 2072-666X; 2072-666X
• DOI: 10.3390/mi14081534

The zeolitic imidazolate framework-67 (ZIF-67) adsorbent and its composites are known to effectively remove organic dyes from aqueous environments. Here, we report a unique crystalline MoS[sub.2]@ZIF-67 nanocomposite adsorbent for the efficient removal of methyl orange (MO) dye from an aqueous medium. In situ synthetic techniques were used to fabricate a well-crystalline MoS[sub.2]@ZIF-67 nanocomposite, which was then discovered to be a superior adsorbent to its constituents. The successful synthesis of the nanocomposite was confirmed using XRD, EDX, FTIR, and SEM. The MoS[sub.2]@ZIF-67 nanocomposite exhibited faster adsorption kinetics and higher dye removal efficiency compared with its constituents. The adsorption kinetic data matched well with the pseudo-second-order model, which signifies that the MO adsorption on the nanocomposite is a chemically driven process. The Langmuir model successfully illustrated the MO dye adsorption on the nanocomposite through comparing the real data with adsorption isotherm models. However, it appears that the Freundlich adsorption isotherm model was also in competition with the Langmuir model. According to the acquired thermodynamics parameters, the adsorption of MO on the MoS[sub.2]@ZIF-67 nanocomposite surface was determined to be spontaneous and exothermic. The findings of this research open an avenue for using the MoS[sub.2]@ZIF-67 nanocomposite to efficiently remove organic dyes from wastewater efflux.