Effect of [Al.sup.3+] additions on the microstructure and photoluminescence of SrTi[O.sub.3]:[Pr.sup.3+] phosphors produced by the sol-gel method

The effect of various concentrations of [Pr.sup.3+] on the structural and luminescent characteristics of SrTi[O.sub.3]:[Pr.sup.3+] phosphors synthesized by the sol-gel method was investigated. Maximum intensity of red luminescence (617 nm) for SrTi[O.sub.3]:[Pr.sup.3+] with excitation by ultraviolet...

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Published inTheoretical and experimental chemistry Vol. 49; no. 3; p. 158
Main Authors Marchylo, O.M, Nakanishi, Y, Kominami, H, Hara, K, Zavyalova, L.V, Svechnikov, S.V, Snopok, B.A
Format Journal Article
LanguageEnglish
Published Springer 01.07.2013
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Summary:The effect of various concentrations of [Pr.sup.3+] on the structural and luminescent characteristics of SrTi[O.sub.3]:[Pr.sup.3+] phosphors synthesized by the sol-gel method was investigated. Maximum intensity of red luminescence (617 nm) for SrTi[O.sub.3]:[Pr.sup.3+] with excitation by ultraviolet radiation is observed at an effective [Pr.sup.3+] concentration of 0.2 mole %. It was shown that the addition of aluminum at the optimum [Pr.sup.3+] concentration leads to deterioration of the crystallinity and reduces brightness of the SrTi[O.sub.3]:[Pr.sup.3+] luminescence. The reason for the last effect may be the presence of minute amounts of iron impurity in the initial reagents. Key words: phosphor, SrTi[O.sub.3]:[Pr.sup.3+], photoluminescence, aluminum, iron.
ISSN:0040-5760
1573-935X