PALLADIUM-CATALYZED ARYLATION/ALKYLATION OF NON-CONJUGATED DIENES

The present invention provides a method for the $i(alpha), $i(omega)-arylation/alkylation of a non-conjugated diene in one step by reacting the diene with an aryl iodide or an aryl bromide and a carbon nucleophile in the presence of an amount of a Pd(O) complex effective to catalyze the reaction. L&...

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Bibliographic Details
Main Author LAROCK, RICHARD, D
Format Patent
LanguageEnglish
Published 21.01.1993
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
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Summary:The present invention provides a method for the $i(alpha), $i(omega)-arylation/alkylation of a non-conjugated diene in one step by reacting the diene with an aryl iodide or an aryl bromide and a carbon nucleophile in the presence of an amount of a Pd(O) complex effective to catalyze the reaction. L'invention concerne un procédé pour l'alpha, oméga-arylation/alkylation d'un diène non conjugué en une seule étape en faisant réagir le diène avec un iodure d'aryle ou un bromure d'aryle et un nucléophile de carbone en présence d'une quantité d'un complexe Pd(O) efficace pour catalyser la réaction.
Bibliography:Application Number: WO1992US05753