Plasticizer free caulks and sealants comprising waterborne acrylic polymeric composites and methods for making the same

• Main Authors: Bromm Karl Allen, Jackson Catheryn L, Demarest Victoria A, Lau Willie, Liss Audrey B
• Format: Patent
• Language: English
• Published: 03.10.2017
• Subjects: ADHESIVES; CHEMICAL PAINT OR INK REMOVERS; CHEMISTRY; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS; COMPOSITIONS BASED THEREON; CORRECTING FLUIDS; DYES; FILLING PASTES; INKS; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; POLISHES; THEIR PREPARATION OR CHEMICAL WORKING-UP; USE OF MATERIALS THEREFOR; WOODSTAINS

The present invention provides aqueous caulk or sealant compositions that are substantially free of any plasticizer comprising an aqueous emulsion copolymer having a broad measured glass transition temperature by differential scanning calorimetry (DSC), soft phases and hard phases, and two separate Tan Delta transition temperatures as measured by dimensional mechanical analysis (DMA), (ii) one or more filler in a filler to binder ratio of up to 4:1, and (iii) from 0.2 to 5 wt. % as solids, based on the total weight of the composition, of one or more thickener or rheology modifier. In addition, the invention provides methods of making the composition comprising polymerizing by gradually adding from a flask into a polymerization vessel a soft monomer composition, and, after feeding at least 20 wt. % of such composition in the vessel, gradually adding into the flask a hard comonomer composition, feeding all flask contents into the vessel and polymerizing.