Process and composition for inhibiting the polymerization of cyclopentadiene compounds

• Main Authors: Nissen Felix, Neumann Manfred, Erpeldinger Oliver, Rinker Stefanie, Ludwig Bettina, Watkins Peter, James Phillip R
• Format: Patent
• Language: English
• Published: 15.11.2016
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP

Method for inhibiting polymerization of cyclopentadiene compound involves contacting cyclopentadiene compound (B) with benzenone derivative (A) (I). Method for inhibiting polymerization of cyclopentadiene compound involves contacting cyclopentadiene compound (B) with benzenone derivative (A) of formula (I). R1>,R2> : H, 1-18C alkyl, 3-15C cycloalkyl, 6-15C aryl or 7-15C or phenylalkyl; R3> : -CN, -COOH, -COOR4>, -COR5>, -OCOR8>, -CONR7>R8>, -PO(OR8>)2, -O-R1>0>,-S-R1>1>-R1>2>, -CC-R1>3> or halo; R4>-R6> : 1-18C alkyl, 3-12C cycloalkyl or 6-10C aryl; R7>,R8> : H, 1-15C alkyl (optionally substituted by 1-4C alkylamino, 2-8C dialkylamino or hydroxy), 7-15C phenylalkyl (optionally substituted by hydroxy, 1-4C alkyl, 1-4C alkylamino or 2-8C dialkylamino) or 6-10C aryl (optionally substituted by 1-4C alkyl, 1-4C alkylamino, 2-8C dialkylamino or hydroxy); NR7>R8> : morpholino, piperidino or pyrrolidino; R9>-R1>1> : H, or 1-15C alkyl, 3-15C cycloalkyl, 7-15C phenylalkyl or 6-15C aryl (all optionally substituted by hydroxy, dialkylamino, -OR1>4> or -[O(CH2)y]xH); x : 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10; y : 1, 2, 3 or 4; R1>4> : 1-6C alkyl; R1>2> : 2-pyridyl, 3-pyridyl, 4-pyridyl, 2-thienyl, 3-thienyl, 2-pyrryl, 3-pyrryl, 2-furyl, 3-furyl or 6-15C aryl (all optionally substituted by hydroxy, nitro, amino, cyano, carboxy, aminocarbonyl, halo, 1-8C alkyl, 1-8C alkoxy, 1-8C alkylthio, 1-8C alkylamino, 2-8C dialkylamino or 2-8C carboxylic ester);and R1>3> : H, 1-12C alkyl, or 6-10C aryl (optionally substituted by hydroxy, nitro, amino, cyano, carboxy, aminocarbonyl, halo, 1-8C alkyl, 1-8C alkoxy, 1-8C alkylthio, 1-8C alkylamino, 2-8C dialkylamino or 2-8C carboxylic ester). Independent claims are included for the following: (1) composition, which comprises benzenone derivative (A) and cyclopentadiene compound (B); and (2) usage of benzenone derivative (A) for inhibiting polymerization of cyclopentadiene compound (B). [Image].