Process for brominating butadiene polymers using mixed solvents

Butadiene polymers are brominated using a quaternary ammonium or quaternary phosphonium tribromide as the brominating agent. The bromination is performed in a solvent mixture than contains at least one polyhalogenated alkane and at least one monohalogenated alkane. The process proceeds easily under...

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Bibliographic Details
Main Authors KING BRUCE A, HULL, JR. JOHN W
Format Patent
LanguageEnglish
Published 23.06.2015
Subjects
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
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Summary:Butadiene polymers are brominated using a quaternary ammonium or quaternary phosphonium tribromide as the brominating agent. The bromination is performed in a solvent mixture than contains at least one polyhalogenated alkane and at least one monohalogenated alkane. The process proceeds easily under mild conditions and allows high conversions to be achieved easily.
Bibliography:Application Number: US201113817447