Process for the co-oligomerisation of ethylene and alpha olefins

A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MXa complexes and/or one or more [bis-...

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Main Authors DE BOER ERIC JOHANNES MARIA, VAN DER HEIJDEN HARRY, VAN ZON ARIE, VAN OORT AART BARTUS, DEULING HENDRIKUS HYACINTHUS, ON QUOC AN
Format Patent
LanguageEnglish
Published 03.07.2007
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
COMPOSITIONS BASED THEREON
GENERAL METHODS OF ORGANIC CHEMISTRY
HETEROCYCLIC COMPOUNDS
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC CHEMISTRY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Summary:A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MXa complexes and/or one or more [bis-aryliminepyridine MYp.Lb+][NC-]q complexes; and said process is carried out at an ethylene pressure of less than 2.5 MPa.
Bibliography:Application Number: US20030739715