Process for preparing oxocyclopentene derivatives

A process for preparing oxocyclopentenes of the formula: wherein R1 is hydrogen, lower alkyl or lower alkenyl and R2 is hydrogen, lower alkyl, lower alkenyl, lower alkynyl, substituted or unsubstituted aryl, ar(lower)alkyl, thienyl or cycloalkyl, which comprises subjecting a furan-carbinol of the fo...

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Bibliographic Details
Main Author MINAI; MASAYOSHI
Format Patent
LanguageEnglish
Published 13.11.1990
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Summary:A process for preparing oxocyclopentenes of the formula: wherein R1 is hydrogen, lower alkyl or lower alkenyl and R2 is hydrogen, lower alkyl, lower alkenyl, lower alkynyl, substituted or unsubstituted aryl, ar(lower)alkyl, thienyl or cycloalkyl, which comprises subjecting a furan-carbinol of the formula: wherein R1 is as defined above and R3 is hydrogen, lower alkyl, lower alkenyl, lower alkynyl, substituted or unsubstituted aryl, ar(lower)alkyl, thienyl or cycloalkyl to rearrangement, subjecting the resultant hydroxycyclopentenone of the formula: wherein R1 and R3 are each as defined above to hydrogenation and subjecting the resulting hydroxycyclopentanone of the formula; wherein R1 and R2 are each as defined above to dehydration.
Bibliography:Application Number: US19860831067