Method for improving gasification process rates and yields by means of electrophilic aromatic substitution pretreatment of coal

• Main Authors: SCHLOSBERG; RICHARD H, WRIGHT; FRANKLIN J, HARTGERINK; RONALD L
• Format: Patent
• Language: English
• Published: 07.02.1978
• Subjects: ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; CARBURETTING AIR OR OTHER GASES; CHEMISTRY; DESTRUCTIVE DISTILLATION OF CARBONAGEOUS MATERIALS FORPRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS; FIRELIGHTERS; FUELS; FUELS NOT OTHERWISE PROVIDED FOR; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; LIQUEFIED PETROLEUM GAS; LUBRICANTS; METALLURGY; NATURAL GAS; PEAT; PETROLEUM, GAS OR COKE INDUSTRIES; PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROMSOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K; TECHNICAL GASES CONTAINING CARBON MONOXIDE; TECHNICAL SUBJECTS COVERED BY FORMER USPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ARTCOLLECTIONS [XRACs] AND DIGESTS

Coal is electrophilically aromatically substituted (i.e., alkylated or acylated) in the presence of an alkylating or acylating agent with or without a catalyst under mild conditions to give a treated coal product. This treated coal product may then be solvent extracted to give an extract and an upgraded coal residue, with this residue being subjected to a gasification process procedure or the treated coal product may be subjected to gasification process procedures without any prior extraction being performed. By means of either technique, a material is prepared for which the rate of gasification and the yield of desired product upon gasification is dramatically increased when compared with nonelectrophilically aromatically substituted material (i.e., raw coal). An improved gasification process is disclosed comprising the steps of electrophilically aromatically substituting coal and subjecting such pretreated coal, either extracted or unextracted to gasification process techniques.