DISENTANGLED PVDF FOR HIGH ELECTROMECHANICAL EFFICIENCY THIN FILMS AND FIBERS

• Main Authors: Chen, Jing, Mei, Hao, Ye, Sheng, Ouderkirk, Andrew John, Purvis, II, Lafe Joseph, Boromand, Arman, Jost, Kristy Alana, Dutta, Abhirup
• Format: Patent
• Language: English
• Published: 18.07.2024
• Subjects: AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDEDFOR; SHAPING OR JOINING OF PLASTICS; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL

A polymer article includes an at least partially disentangled polyvinylidene fluoride (PVDF) family member composition and is characterized by an elastic modulus of at least 4 GPa and an electromechanical coupling factor (k31) of at least 0.1 at room temperature. A method of manufacturing such a polymer article may include forming an at least partially disentangled polymer composition into a polymer thin film or fiber, applying a tensile stress to the polymer article in an amount effective to induce a stretch ratio of at least approximately 5 in the thin film or fiber, and applying an electric field across a thickness dimension of the polymer article. Annealing and poling steps may separately or simultaneously accompany and/or follow the act of stretching.