METHOD FOR PREPARING MnO2/CARBON COMPOSITE, MNO2/CARBON COMPOSITE PREPARED BY THE METHOD, AND LITHIUM-AIR SECONDARY BATTERY INCLUDING THE COMPOSITE

• Main Authors: JANG TAE YOUNG, CHUNG KU BONG, LEE HO TAEK, CHOI JINSUB, RYU KYOUNG HAN, TAK YONGSUG, BAECK SUNG-HYEON
• Format: Patent
• Language: English
• Published: 31.01.2013
• Subjects: APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL; BASIC ELECTRIC ELEMENTS; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; ELECTRICITY; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL; PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY; REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION; SPRAYING OR ATOMISING IN GENERAL; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE; THEIR RELEVANT APPARATUS; TRANSPORTING

Disclosed is a method for preparing an MnO2/carbon composite for a lithium-air secondary battery by preparing a precursor solution by dissolving permanganate powder in distilled water, preparing a MnO2/carbon composite by dispersing carbon in the precursor solution and using a reducing agent, and mixing the MnO2/carbon composite with polyvinylidene fluoride (PVdF) and supporting the mixture on nickel foam. According to the method for preparing a MnO2/carbon composite for a lithium-air secondary battery, the MnO2/carbon composite is prepared by dispersing carbon in a permanganate solution, instead of simply mixing carbon with manganese oxide, and thus the binding force between carbon and manganese oxide and the dispersion of carbon in manganese oxide can increase. The MnO2/carbon composite prepared by the above method has improved catalytic performance as an air electrode for a lithium-air secondary battery and thus can be effectively used as an electrode material for lithium-air secondary batteries.