HEAVY OIL CONVERSION PROCESS WITH IN-SITU POTASSIUM SULFIDE GENERATION

• Main Authors: BAIRD, JR. WILLIAM C, VANN WALTER D, LETA DANIEL P, SOTO JORGE L, MCCONNACHIE JONATHAN M
• Format: Patent
• Language: English
• Published: 20.09.2012
• Subjects: CHEMISTRY; COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM,RUBIDIUM, CAESIUM, OR FRANCIUM; COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM,CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THERARE-EARTH METALS; COMPOUNDS THEREOF; CRACKING HYDROCARBON OILS; FUELS; INORGANIC CHEMISTRY; LUBRICANTS; METALLURGY; MINERAL WAXES; NON-METALLIC ELEMENTS; PEAT; PERFORMING OPERATIONS; PETROLEUM, GAS OR COKE INDUSTRIES; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; SEPARATION; TECHNICAL GASES CONTAINING CARBON MONOXIDE; TRANSPORTING

The present invention relates to a process for regeneration of alkali metal salt reagent used in desulfurization of heavy oil feedstreams. In particular, the it present invention relates to a process utilizing potassium hydroxide as an external supply reagent to a heavy oil conversion process and in-situ conversion of the spent reactants utilized in such process into a potassium sulfide reagent for reintroduction into the heavy oil conversion process.