ACRYLATE-BASED FLUORINATED COPOLYMERS FOR HIGH-SOLIDS COATINGS

• Main Authors: SOUCEK MARK D, TEMPLEMAN CYNTHIA G, ALYAMAC ELIF, ISHII MASAHIKO
• Format: Patent
• Language: English
• Published: 05.04.2012
• Subjects: ADHESIVES; CHEMICAL PAINT OR INK REMOVERS; CHEMISTRY; COATING COMPOSITIONS, e.g. PAINTS, VARNISHES ORLACQUERS; CORRECTING FLUIDS; DYES; FILLING PASTES; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; INKS; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; PAINTS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; POLISHES; TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION; TECHNICAL SUBJECTS COVERED BY FORMER USPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; USE OF MATERIALS THEREFOR; WOODSTAINS

A series of low, medium, and high molecular weight copolymers containing methyl methacrylate, n-butyl acrylate. 2-hydroxyethyl methacrylate, and 2,2,2-trifluoroethyl methacrylate were synthesized by solution polymerization under monomer-starved conditions. The copolymers were crosslinked with a methylated melamine formaldehyde resin in order to obtain thermosetting acrylics. Lower wettability, higher oxygen permeability, and lower refractive index were observed for higher concentrations of fluorinated monomer in the copolymer composition and high number-average hydroxyl functionality of the high molecular weight copolymers increased the crosslink density of the acrylic films, thereby resulting in improved tensile strength and tensile modulus.