PRIMARY ALLYLIC ALCOHOL AND AG

The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2′,6,6′-tetra-methylpiperidin-1-oxyl) or its derivates and c) a co-...

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Bibliographic Details
Main Authors BONRATH WERNER, ECKHARDT JEAN-FRANCOIS, HINZE RAMONA, VALKENBERG MICHAEL H, EGGERSDORFER MANFRED L, HOELDERICH WOLFGANG F
Format Patent
LanguageEnglish
Published 20.01.2011
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
CHEMISTRY
HETEROCYCLIC COMPOUNDS
METALLURGY
ORGANIC CHEMISTRY
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Summary:The invention relates to a process of reacting a primary allylic alcohol with a compound containing a) a metal selected from the group consisting of Ag, Au, Ce, Mn, Ni, Ru, Re, Zn and Co preferably Ag and b) an oxidant like TEMPO (2,2′,6,6′-tetra-methylpiperidin-1-oxyl) or its derivates and c) a co-oxidants selected from the group of peroxodisulfates (PDS), H2505, H2O2, NaOCl, O2, KOCl, and air.
Bibliography:Application Number: US20080526860