LITHIUM-SULPHUR BATTERY WITH HIGH SPECIFIC ENERGY

• Main Authors: KOLOSNITSYN VLADIMIR, KARASEVA ELENA
• Format: Patent
• Language: English
• Published: 16.09.2010
• Subjects: BASIC ELECTRIC ELEMENTS; CIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTINGELECTRIC POWER; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER; ELECTRICITY; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERATION; PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSIONOF CHEMICAL INTO ELECTRICAL ENERGY; REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGYGENERATION, TRANSMISSION OR DISTRIBUTION; SYSTEMS FOR STORING ELECTRIC ENERGY; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINSTCLIMATE CHANGE

The invention provides for a method of discharging a chemical source of electric energy in two stages. The chemical source of electric energy comprises a positive electrode (cathode) including sulphur or sulphur-based organic compounds, sulphur-based polymeric compounds or sulphur-based inorganic compounds as a depolarizer, a negative electrode (anode) made of metallic lithium or lithium-containing alloys, and an electrolyte comprising a solution of at least one salt in at least one aprotic solvent. The method comprises the steps of configuring the chemical source of electric energy to generate soluble polysulphides in the electrolyte during a first stage of a two stage discharge process, and selecting the quantity of sulphur in the depolariser and the volume of electrolyte in a way that after the first stage discharge of the cathode, the concentration of the soluble polysulphides in the electrolyte is at least seventy percent (70%) of a saturation concentration of the polysulphides in the electrolyte.