AROMATIC-ALIPHATIC POLYESTER HOT MELT ADHESIVES FOR ROLL-APPLIED LABELS

• Main Authors: WILLIAMS FREDDIE WAYNE, DONELSON MICHAEL EUGENE, SHELBY MARCUS DAVID, ROBE GARY ROBERT, CANNON JOSHUA SETH, GEORGE SCOTT ELLERY, TANNER CANDACE MICHELE
• Format: Patent
• Language: English
• Published: 06.05.2010
• Subjects: ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; ADHESIVES; CHEMISTRY; COMPOSITIONS BASED THEREON; DYES; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; LAYERED PRODUCTS; LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT ORNON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; PERFORMING OPERATIONS; POLISHES; TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION; TECHNICAL SUBJECTS COVERED BY FORMER USPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; USE OF MATERIALS AS ADHESIVES

Disclosed are hot-melt adhesives prepared from aromatic-aliphatic polyesters containing terephthalic acid in combination with adipic acid, glutaric acid, or a mixture thereof, as diacid components and a diol component containing 1,4-butanediol, 1,6-hexanediol, or a combination thereof. These adhesives set up rapidly within a well-defined temperature window. The hot-melt adhesives can be used in a variety of applications, but are especially suited as seaming adhesives for roll-applied labels. These adhesives have melting temperatures and crystallization properties that allow their application at temperatures cool enough to prevent curling and premature shrinkage of the shrink label during seaming, and yet produce strong label seams that can withstand the elevated temperatures of a shrink tunnel without sacrificing line speed. Also disclosed are labeled containers and a process for applying a roll-on, shrink label to a container using the hot-melt adhesives of the invention.