Method for the Continuous Preparation of a Catalytic System that is Used to Polymerize a Conjugated Diene and Installation for Implementing Same

• Main Authors: KIENER PIERRE, MARTINET FABRICE, BARBOTIN FANNY, ANSELME BERNARD, PAROLA HELENE
• Format: Patent
• Language: English
• Published: 16.07.2009
• Subjects: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; THEIR PREPARATION OR CHEMICAL WORKING-UP; THEIR RELEVANT APPARATUS; TRANSPORTING

The present invention relates to a process for the continuous preparation of a catalytic system that can be used for the polymerization of at least one conjugated diene monomer, said catalytic system being based on at least: a preforming conjugated diene; an organic phosphoric acid salt of one or more rare-earth metal(s), said salt being in suspension in at least one saturated aliphatic or alicyclic and inert hydrocarbon-based solvent; an alkylating agent comprising an alkylaluminium having the formula AlR3 or HAlR2; and a halogen donor comprising an alkylaluminium halide; characterized in that it comprises successively in one line (L): (i) a reaction between the preforming conjugated diene, with the solution of the salt of rare-earth element(s) and the alkylating agent, with the alkylation reaction being carried out for a characteristic minimum period of at least 5 minutes in an alkylation reactor (30) composed of at least one well-mixed dynamic mixer; (ii) the addition of said halogen donor to the mixture obtained in (i), in order to produce a reaction for the halogenation-ageing of the preformed catalytic system and to continuously produce said preformed catalytic system at the outlet of said line (L).