Copolymers of vinyl-and allylsilanes

Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The...

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Bibliographic Details
Main Authors WANG YING, MCLAIN STEPHAN J, ITTEL STEVEN DALE, WANG LIN, IONKIN ALEX SERGEY, SWEETMAN KARL J, JOHNSON LYNDA KAYE, SCHIFFINO RINALDO S, RADZEWICH CHATHERINE E, BENNETT ALISON MARGARET ANNE, MCCORD ELIZABETH FORRESTER
Format Patent
LanguageEnglish
Published 04.06.2009
Subjects
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Summary:Ethylene and allyl- or vinylsilanes are efficiently copolymerized by certain late transition metal complexes containing selected bidentate or tridentate ligands. The resulting novel polymers may be crosslinked by moisture when vinylsilane contains groups bound to silicon which are hydrolyzable. The polymers are useful for wire coating, crosslinked foams, pipes, and other uses.
Bibliography:Application Number: US20070002925