Method for producing carboxylic acid by alcohol oxidation

The invention relates to a method for oxidizing primary amino alcohols, primary or secondary alkenols or alkinols into the corresponding acids or ketones. According to said method, a primary amino alcohol or a primary or secondary alkenol or alkinol is oxidized in the form of a substrate, in the pre...

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Bibliographic Details
Main Authors SCHMIEDER-VAN DE VONDERVOORT ELISABETH, BOUTTEMY SABINE, PADRON CARILLO JOSE, ALSTERS PAUL
Format Patent
LanguageEnglish
Published 06.03.2003
Edition7
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Summary:The invention relates to a method for oxidizing primary amino alcohols, primary or secondary alkenols or alkinols into the corresponding acids or ketones. According to said method, a primary amino alcohol or a primary or secondary alkenol or alkinol is oxidized in the form of a substrate, in the presence of an equimolar quantity of periodate or a molar excess thereof in relation to the alcoholic hydroxy groups and catalytic quantities of dichromate or CrO3 and in the presence of an acid in water, a water/solvent mixture or a solvent at a temperature of -20 ° C. to +50 ° C., to produce the corresponding acid or the corresponding ketone.
Bibliography:Application Number: US20020168849