Methods for preparing ruthenium carbene complexes and precursors thereto
Methods of preparing ruthenium carbene complex precursors are disclosed herein. In some embodiments, the methods include reacting a ruthenium refinery salt with an L-type ligand and a reducing agent to form the ruthenium carbene complex precursor. Methods of preparing a ruthenium vinylcarbene comple...
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Main Authors | , |
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Format | Patent |
Language | English |
Published |
21.05.2019
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Subjects | |
Online Access | Get full text |
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Summary: | Methods of preparing ruthenium carbene complex precursors are disclosed herein. In some embodiments, the methods include reacting a ruthenium refinery salt with an L-type ligand and a reducing agent to form the ruthenium carbene complex precursor. Methods of preparing a ruthenium vinylcarbene complex are also disclosed. In some embodiments, preparing a ruthenium carbene complex includes converting a ruthenium carbene complex precursor into a ruthenium carbene complex having a structure (PR1R2R3)2Cl2Ru═CH-R4, wherein R1, R2, R3, and R4 are defined herein. |
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Bibliography: | Application Number: US201615334771 |