Use of heterogeneous acid catalysts based on mixed metal salts to produce biodiesel

• Main Authors: Murrieta Guevara, Florentino Rafael, Rodriguez Rodriguez, Javier Esteban, Martinez Guerrero, Maria del Carmen, Jaramillo Jacob, Alicia del Rayo, Castaneda Lopez, Luis Carlos, Marin Rosas, Celia, Jimenez Cruz, Federico Jesus, Hernandez Suarez, Rogelio
• Format: Patent
• Language: English
• Published: 04.09.2018
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE ORUNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; ANIMAL AND VEGETABLE OILS, FATS, FATTY SUBSTANCES AND WAXES; CANDLES; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; DETERGENTS; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS,OILS, OR FATTY ACIDS OBTAINED THEREFROM; FATTY ACIDS FROM FATS, OILS OR WAXES; FATTY ACIDS THEREFROM; FIRELIGHTERS; FUELS; FUELS NOT OTHERWISE PROVIDED FOR; LIQUEFIED PETROLEUM GAS; LUBRICANTS; METALLURGY; NATURAL GAS; ORGANIC CHEMISTRY; PEAT; PERFORMING OPERATIONS; PETROLEUM, GAS OR COKE INDUSTRIES; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BYSUBCLASSES C10G, C10K; TECHNICAL GASES CONTAINING CARBON MONOXIDE; THEIR RELEVANT APPARATUS; TRANSPORTING

The present invention relates to the production of biodiesel and alkyl esters by the transesterification of triglyceride esters, with alcohols in heterogeneous phase in the presence of heterogeneous catalysts, with yields higher than 80%, at a temperature from 0 to 300° C., residence time from 20 minutes to 20 h, space velocity of 0.1 to 10 h−1, pressure of 25-100 kg/cm2 (24.5-98.07 bar), methanol/oil molar ratio of 10 to 40 and catalyst concentration of 0.001 to 20 weight % based on tri-, di- or monoglyceride. The method produces biodiesel and alkyl esters by transesterification of tri-, di- or mono-glycerides, from palm, jatropha, castor, soybean and sunflower oils, wherein the alcohoxyls R1O, R2O and R3O of the glycerides are C1 to C24 and a C1-C4 alcohol, such as methanol, in an alcohol:oil ratio from 3:1 to 50:1. The transesterification reaction produces biodiesel while avoiding loss of catalyst, contaminating liquid effluents and eliminating undesirable hydrolysis of triglycerides, diglycerides and monoglycerides into free fatty acids and saponification that generate soaps.