PROCESS TO OBTAIN RANDOM COPOLYMERS DERIVED FROM ITACONIC ACID AND/OR ITS ISOMERS AND SODIUM ALKENYL SULFONATES AND USE OF THE PRODUCT THEREOF

• Main Authors: ERICK EMANUEL LUNA ROJERO, ALEJANDRO RAMIREZ ESTRADA, RAUL HERNANDEZ ALTAMIRANO, VIOLETA YASMIN MENA CERVANTES, JOSE MANUEL MARTINEZ MAGADAN, DAVID AARON NIETO ALVAREZ, MARIA DEL PILAR ARZOLA GARCIA, LUIS SILVESTRE ZAMUDIO RIVERA, MIRNA PONS JIMENEZ
• Format: Patent
• Language: English
• Published: 09.11.2015
• Subjects: CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE

The present invention relates to the process for obtaining random copolymers based on itaconic acid and/or isomers and sodium alkenyl sulfonates, by means of polymerization in aqueous solution via free radicals at an acidic pH in the range from 1.0 to 3.5 and with a redox system as initiator, and the use thereof as calcium carbonate and calcium, strontium and barium sulfates mineral scale inhibitors and as dispersants of clays, iron oxides, calcium carbonate and strontium, barium and calcium sulfates. Random copolymers prevent and control damage to the formation by mineral salts scale that occurs in an oil reservoir, obstruction of water injection and crude oil production pipelines, as well as in production rigs due to mineral scale precipitation, all this as a consequence of high levels of salinity of the formation water and incompatible mixtures of injection water and formation water. Random copolymers are characterized for being tolerant to high concentrations of divalent ions, such as calcium, magnesium, strontium and barium, and by the fact that for its application to the reservoir and to injection or production pipelines, treated water, sea water and water that is characteristic of the reservoir (formation water) can be used as means of transportation. On the other hand, the copolymers can also be used to inhibit and disperse mineral scale occurring in cooling systems and boilers used in the oil and chemistry industry. Furthermore, the random copolymers of the present invention are characterized for meeting internationally established environmental standards and are classified as particularly non-toxic and therefore they can be used in pipelines and equipment from oil and chemical industry that uses fresh water and sea water that are characteristic of offshore and inland facilities.