INSECTICIDAL COMPOUNDS

• Main Authors: PETER RENOLD, JÉRÔME YVES CASSAYRE, MYRIEM EL QACEMI, THOMAS PITTERNA, JULIE CLEMENTINE TOUEG
• Format: Patent
• Language: English; Spanish
• Published: 05.03.2014
• Subjects: AGRICULTURE; ANIMAL HUSBANDRY; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES; CHEMISTRY; FISHING; FORESTRY; HETEROCYCLIC COMPOUNDS; HUMAN NECESSITIES; HUNTING; METALLURGY; ORGANIC CHEMISTRY; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS; PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTSTHEREOF; TRAPPING

The present invention provides compounds of formula (I): wherein A1, A2, A3 and A4 are independently of one another C-H, C-R5, or nitrogen; B1--B2--B3--B4 is -CH2-C=N-CH2-, -CH2-N-CH2-CH2-, -CH2-C=CH-0- or -CH=C-CH2-0-; G1 is oxygen or sulfur; L is a single bond or C1-C8alkylene; R1 is hydrogen, C1-C8alkyl, C1-C8alkylcarbonyl-, C1-C8alkoxy, C2-C8alkenyl, C2-C8alkynyl, C1-C8alkoxy- C1-C8alkyl, aryl or aryl substituted by one to three R6, or R1 is heterocyclyl or heterocyclyl substituted by one to three R6 or C1-C8alkoxycarbonyl-; R2 is hydrogen, C1-C8haloalkyl or C1-C8alkyl; R3 is C1-C8haloalkyl; R4 is aryl or aryl substituted by one to three R6, or R4 is heterocyclyl or heterocyclyl substituted by one to three R6; Y1 is CR7R8, C=O or C=S; Y2, Y3 and Y4 are independently CR7R8, C=0, C=S, N-R9, O, S, SO or SO2; wherein at least two adjacent ring atoms in the ring formed by Y1, Y2, Y3 and Y4 are heteroatoms; each R7 and R8 is independently hydrogen, halogen, C1-C8alkyl, or C1-C8haloalkyl; and R5, R6, R7, R8 and R9 are as defined in the claims. The invention also relates to processes and intermediates for preparing these compounds, to insecticidal, acaricidal, nematicidal and molluscicidal compositions comprising these compounds and to methods of using these compounds to control insect, acarine, nematode and mollusc pests. La presente invención proporciona compuestos de fórmula (I) (Ver Formula) donde A1, A2, A3 y A4 son, independientemente unos de otros, CH, C-R5 o nitrógeno; B1--B2--B3-B4 es -CH2-C=N-CH2-, -CH2-N-CH2-CH2-, -CH2-C=CH- O- o -CH=C-CH2-O-; G' es oxígeno o azufre; L es un enlace sencillo o alquileno C,-C8 R1 es hidrógeno, alquilo C1-C8, (alquil C1-C8)carbonil-, alcoxi C1-C8, alquenilo C2-C8, alquinilo C2-C8, (alcoxi C1-C8)- (alquilo C1-C8), arilo o arilo sustituido con de uno a tres R6, o R1 es heterociclilo o heterociclilo sustituido con de uno a tres R6 o (alcoxi C1-C8)carbonil-; es hidrógeno, haloalquilo C1-C8 o alquilo C1-C8 R3 es haloalquilo C,-C8 R4 es arilo o arilo sustituido con de uno a tres R6, o R4 es heterociclilo o heterociclilo sustituido con de uno a tres R6 Y1 es CR7R8, C=O o C=S; Y2, Y3 e Y4 son independientemente CR7R8, C=O, C=S, N-R9, O, S, SO o SO2 donde al menos dos átomos del anillo adyacentes en el anillo formado por Y1, Y2, Y3 e Y4 son heteroátomos; cada R7 y R8 es independientemente hidrógeno, halógeno, alquilo C1-C8 o haloalquilo C1-C8; y R5, R6, R7, R8 y R9 son como se definen en las reivindicaciones. La invención también se refiere a procesos e intermedios para preparar estos compuestos, a composiciones insecticidas, acaricidas, nematicidas y molusquicidas que comprenden estos compuestos y a métodos para emplear estos compuestos con el fin de controlar plagas de insectos, acáridos, nematodos y moluscos.