신규 오가노폴리실록산 또는 그의 산 중화 염, 및 그것들의 용도

• Main Authors: TAMURA SEIKI, PETROFF LENIN JAMES, JOFFRE ERIC JUDE
• Format: Patent
• Language: Korean
• Published: 09.01.2019
• Subjects: ADHESIVES; CHEMISTRY; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; DYES; HUMAN NECESSITIES; HYGIENE; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE; MEDICAL OR VETERINARY SCIENCE; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; POLISHES; PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES; THEIR PREPARATION OR CHEMICAL WORKING-UP

폴리옥시알킬렌 구조 등을 함유하지 않는, PEG-FREE 구조이면서, 뛰어난 계면 활성능 및 유제로서의 특성을 가지고, 또한 종래의 친수성 실리콘 재료에서는 실현 곤란했던, 이온성 매니지먼트 및 점도 매니지먼트가 가능하고, 또한 유제로서 특이한 성질을 구비한, 처방 설계 기술자에게 있어서의 배합이나 설계의 자유도를 크게 확장하는 신규한 실리콘 재료 및 그의 용도를 제공하는 것을 목적으로 한다. 본 발명의 실리콘 재료는 식: -CH-O-CH-CH(OH)-CH-N(R)(R)(식 중, q는 1∼6의 범위의 수이며, R및 R는 관능기 중에 질소 원자를 함유하지 않고, 할로겐 원자에 의해 치환 또는 비치환의 1가 탄화수소기 또는 알칸올 기이며, R및 R중 어느 한쪽은 하이드록실기를 가지고, 또한 R및 R중의 하이드록실기의 합계수는 3 이하이다)로 표시되는 3급 아민 구조를 함유하고, 분자쇄 측쇄에 결합한 친수성 기를 함유하는, 신규한 오가노폴리실록산 또는 그의 산 중화 염이다. An object is to provide a novel silicone material that has an excellent surface activity ability and characteristics of an oil agent while being a material of a PEG-Free structure including no polyoxyalkylene structure and the like, enables ionic management and viscosity management which have been difficult to implement with conventional hydrophilic silicone materials, and has a unique property of an oil agent, to largely increase a degree of freedom of compounding and designing for a formulation technician, and to provide an application of the material. A silicone material according to the present invention is a novel organopolysiloxane or acid-neutralized salt thereof that contains a side-chain bonded hydrophilic group having tertiary-amine structure and represented by Formula: -C q H 2q -O-CH 2 -CH(OH)-CH 2 -N(R Q1 )(R Q2 ) (wherein q is a number ranging from 1 to 6, R Q1 and R Q2 are a halogen-substituted or non-substituted monovalent hydrocarbon group or alkanol group, at least one of R Q1 and R Q2 has a hydroxyl group, but total number of hydroxyl groups in R Q1 and R Q2 is 3 or less), and any of R Q1 and R Q2 does not have a nitrogen atom in the group.