복합 물품 및 그의 제조 방법

• Main Authors: SPAGNOLA JOSEPH C, KLUN THOMAS P, WEIGEL MARK D, LYONS CHRISTOPHER S, CLOUGH ROBERT S
• Format: Patent
• Language: Korean
• Published: 30.03.2018
• Subjects: AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F,C08G; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL; CHEMICAL SURFACE TREATMENT; CHEMISTRY; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATIONOR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY IONIMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; COATING MATERIAL WITH METALLIC MATERIAL; COATING METALLIC MATERIAL; COMPOSITIONS BASED THEREON; COMPOSITIONS OF MACROMOLECULAR COMPOUNDS; DIFFUSION TREATMENT OF METALLIC MATERIAL; GENERAL PROCESSES OF COMPOUNDING; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION INGENERAL; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TOSURFACES, IN GENERAL; SPRAYING OR ATOMISING IN GENERAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THESURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; THEIR PREPARATION OR CHEMICAL WORKING-UP; TRANSPORTING; WORKING-UP

복합 물품은 기재, 베이스 중합체 층, 무기 배리어 층, 및 상부 중합체 층을 포함한다. 베이스 중합체 층은 기재 상에 배치되고, 하기 화학식으로 나타낸 적어도 하나의 다이(메트)아크릴레이트를 적어도 60 중량% 포함하는 성분들의 중합된 반응 생성물을 포함한다:상기 식에서, 각각의 R은 독립적으로 H 또는 메틸이고, 각각의 R는 독립적으로 1 내지 4개의 탄소 원자를 갖는 알킬 기를 나타내거나, 또는 2개의 R기는 함께 2 내지 7개의 탄소 원자를 갖는 알킬렌 기를 형성할 수 있다. 무기 배리어 층은 베이스 중합체 층에 접합된다. 상부 중합체 층은 기재의 반대편에서, 무기 배리어 층 상에 배치되며, 상부 중합체 층은 13 내지 24개의 탄소 원자를 갖는 지환족 (메트)아크릴레이트를 적어도 60 중량% 포함하는 성분들의 중합된 반응 생성물을 포함한다. A composite article comprises a substrate, base polymer layer, an inorganic barrier layer, and top polymer layer. The base polymer layer is disposed on the substrate, and includes a polymerized reaction product of components comprising at least 60 percent by weight of at least one di(meth)acrylate represented by the formula wherein: each R1 is independently H or methyl; and each R2 independently represents an alkyl group having from 1 to 4 carbon atoms, or two R2 groups may together form an alkylene group having from 2 to 7 carbon atoms. An inorganic barrier layer is bonded to the base polymer layer. The top polymer layer is disposed on the inorganic barrier layer opposite the substrate, wherein the top polymer layer comprises a polymerized reaction product of components comprising at least 60 percent by weight of a cycloaliphatic (meth)acrylate having from 13 to 24 carbon atoms.