CYCLOALKANE OXIDATION CATALYSTS AND METHOD TO PRODUCE ALCOHOLS AND KETONES

• Main Authors: OCAMPO FABIEN, BORONAT MERCEDES, LOPEZ AUSENS JAVIER TIRSO, CORMA AVELINO, CHOUZIER SANDRA, MASTROIANNI SERGIO
• Format: Patent
• Language: English; Korean
• Published: 04.09.2017
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; COMPOSITIONS BASED THEREON; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; METALLURGY; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; THEIR PREPARATION OR CHEMICAL WORKING-UP; THEIR RELEVANT APPARATUS; TRANSPORTING

본 발명은 시클로알칸을 산화시켜서 상응하는 알콜 및 케톤을 함유하는 생성 혼합물을 형성하는 방법에 관한 것이며, 상기 방법은 시클로알칸을 촉매 유효량의 산화세륨 기재 촉매의 존재하에서 히드로퍼옥사이드 화합물과 접촉시키는 단계를 포함한다. The present invention concerns a method of oxidizing a cycloalkane to form a product mixture containing a corresponding alcohol and ketone, said method comprising contacting a cycloalkane with a hydroperoxide compound in the presence of a catalytic effective amount of a cerium oxide based catalyst.