12- ETHERAMINES BASED ON 12-DIALCOHOLS

• Main Authors: SCIALLA STEFANO, EBERT SOPHIA, LOUGHNANE BRIAN J, WIGBERS CHRISTOF WILHELM, BOECKH DIETER, CHRISTMAS KEVIN, HUELSKOETTER FRANK, LUDOLPH BJOERN, REES DARREN
• Format: Patent
• Language: English; Korean
• Published: 29.11.2016
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; ADHESIVES; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; COMPOSITIONS BASED THEREON; DYES; HUMAN NECESSITIES; HYGIENE; MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS; MEDICAL OR VETERINARY SCIENCE; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ORGANIC CHEMISTRY; ORGANIC MACROMOLECULAR COMPOUNDS; PAINTS; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; POLISHES; PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES; SPECIFIC USE OF COSMETICS OR SIMILAR TOILETPREPARATIONS; THEIR PREPARATION OR CHEMICAL WORKING-UP; THEIR RELEVANT APPARATUS; TRANSPORTING; USE OF MATERIALS AS ADHESIVES

본 발명은 1,2-디알코올 기재의, 식 (I) 또는 식 (II) 의 에테르아민, 또는 식 (I) 및 식 (II) 의 에테르아민의 혼합물:[식 중, R은 2 내지 16 개의 탄소 원자를 갖는 선형 또는 분지형 알킬기이고, R는 수소 또는 1 내지 16 개의 탄소 원자를 갖는 알킬기이고, x≥1 및 y≥1 이고, x+y 의 합계는 2 내지 10 이고, A, A, A및 A는 독립적으로 2 내지 18 개의 탄소 원자를 갖는 선형 및/또는 분지형 알킬렌으로 이루어진 군으로부터 선택되고, Z-Z는 독립적으로 OH, NH, NHR' 또는 NR'R" 로부터 선택되고, Z-Z중 하나 이상 및 Z-Z중 하나 이상은 NH, NHR' 또는 NR'R" 이며, 이때 R' 및 R" 는 독립적으로 2 내지 6 개의 탄소 원자를 갖는 알킬렌으로부터 선택됨]. 본 발명은 추가로 1,2-디알코올의 알콕실화 및 아미노화에 의해 수득가능한 에테르아민에 관한 것이다. The invention relates to etheramines of formula (I) or formula (II) or a mixture of etheramines of formula (I) and formula (II) based on 1,2-dialcohols, wherein R1 is a linear or branched alkyl group with 2 to 16 carbon atoms, R2 is a hydrogen or an alkyl group with 1 to 16 carbon atoms, x≥1 and y≥1 and the sum of x+y is between 2 and 10, and A1, A2, A3 and A4 are independently selected from the group consisting of linear and/or branched alkylenes having 2 to 18 carbon atoms and wherein Z1-Z4 are independently selected from OH, NH2, NHR' or NR'R", wherein at least one of Z1-Z2 and at least one of Z3-Z4 is NH2, NH R' or NR'R", wherein R' and R" are independently selected from alkylenes having 2 to 6 carbon atoms. (II) The invention further relates to etheramines obtainable by the alkoxylation and amination of 1,2- dialcohols.