PROCESS FOR THE PRODUCTION OF OLEFINS

• Main Authors: REID IAN ALLAN BEATTIE, LITTLE IAN RAYMOND
• Format: Patent
• Language: English
• Published: 29.08.2005
• Edition: 7
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; CHEMISTRY; CRACKING HYDROCARBON OILS; FUELS; LUBRICANTS; METALLURGY; MINERAL WAXES; ORGANIC CHEMISTRY; PEAT; PETROLEUM, GAS OR COKE INDUSTRIES; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVEHYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, ORGASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; TECHNICAL GASES CONTAINING CARBON MONOXIDE

A process for the production of olefins from a hydrocarbon comprising the steps of: a) passing a first feed stream comprising gaseous reactants to a first reaction zone wherein said gaseous reactants react exothermically to provide a product stream b) producing a mixed feed stream comprising oxygen by passing the product stream produced in step (a) and a second feed stream comprising a hydrocarbon feedstock to a mixing zone, oxygen being passed to the mixing zone via (i) the product stream produced in step (a), (ii) the second feed stream comprising a hydrocarbon feedstock and/or (iii) a third stream comprising an oxygen- containing gas c) passing the mixed feed stream directly to an essentially adiabatic second reaction zone wherein in the absence of a supported platinum group metal catalyst at least a part of the oxygen is consumed and a stream comprising olefins is produced e) cooling the stream comprising olefins exiting the second reaction zone to less than 650°C within less than 150 milliseconds of formation and wherein the temperature of the mixed stream is at least 500°C, the mixing zone and the second reaction zone are maintained at a pressure of between 1.5-50 bar and the residence time within the mixing zone is less than the autoignition delay for the mixed stream.