Fluorinated triazinic compounds

• Main Authors: CARIGNANO GABRIELLA, SAVARINO PIERO, BARATTA PAOLO, VISCA MARIO, RUSSO ANTONIO
• Format: Patent
• Language: English; Korean
• Published: 26.01.2001
• Edition: 7
• Subjects: ADHESIVES; CHEMISTRY; DYEING LEATHER, FURS, OR SOLID MACROMOLECULAR SUBSTANCES INANY FORM; DYEING OR PRINTING TEXTILES; DYES; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR; HETEROCYCLIC COMPOUNDS; LAUNDERING; MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FORELSEWHERE; METALLURGY; MISCELLANEOUS APPLICATIONS OF MATERIALS; MISCELLANEOUS COMPOSITIONS; NATURAL RESINS; ORGANIC CHEMISTRY; PAINTS; POLISHES; TEXTILES; TREATMENT OF TEXTILES OR THE LIKE; TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS,FABRICS, FEATHERS, OR FIBROUS GOODS MADE FROM SUCH MATERIALS

PURPOSE: A fluorinated triazine compound capable of imparting water repellency and oil repellency and excellent softness to a textile without substantially changing the surface appearance of the textile and capable of sustaining their effects after repeated washing with water or solvent. CONSTITUTION: The fluorinated triazine compound expressed by formulas I or II wherein Z is -SO2-, -CO or the like; Y is -O-, -S- or the like; Rf is a (per) fluoropolyether chain comprising a repeating unit selected from a 1-30C fluoroalkyl, a -(CF(CF3)-CF2O)- or the like; X is Cl or the like is obtained. The compound of formulas I or II is obtained by reacting alcohol of formula III with 2,4,6-trichloro-1,3,5-triazine of formula IV, preferably under the presence of a hydrochloride acceptor such as tetrahydrofuran or the like. The compound of formulas I or II is preferably used 0.1-20 wt.% of the gross weight of the textile. 다음 식을 가지는 플루오르화된 트리아진 화합물: 여기서 Z = T-Y이고, T = -(CH), -SO, -CO이고, q = 는 1 내지 20 사이의 정수이고; Y = O-, O(CHO)-, O(CH)-NR-, O(CH)-O-, O(CHO)-, NR-, S-, S(CHO)-이고; 여기서 R = H, 1 내지 10 사이의 탄소원자를 가지는 알킬; p는 1 내지 5 사이의 정수; R는 선형 또는 가지난 플루오로알킬 체인 또는 (퍼)플루오로폴리에테르 체인을 나타낸다. X는 다음에서 선택된다: Cl; R- CF- Z; CF-Z. 천연 또는 합성 섬유직물의 처리를 위한 이들 트리아진 화합물 또는 퍼뮬레이션(formulation)의 용도.