PHOTOPOLYMERIZABLE COMPOSITION

• Main Authors: TANJI MAKOTO, KAKUMARU HAJIME, HAYASHI NOBUYUKI
• Format: Patent
• Language: English
• Published: 28.08.1985
• Subjects: APPARATUS SPECIALLY ADAPTED THEREFOR; AUXILIARY PROCESSES IN PHOTOGRAPHY; BASIC ELECTRIC ELEMENTS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; CHEMISTRY; CINEMATOGRAPHY; COMPOSITIONS BASED THEREON; ELECTRIC SOLID STATE DEVICES NOT OTHERWISE PROVIDED FOR; ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR; ELECTRICITY; ELECTROGRAPHY; HOLOGRAPHY; MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS; MATERIALS THEREFOR; METALLURGY; ORGANIC MACROMOLECULAR COMPOUNDS; ORIGINALS THEREFOR; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR,STEREO-PHOTOGRAPHIC PROCESSES; PHOTOGRAPHY; PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES,e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTORDEVICES; PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHYSICS; PRINTED CIRCUITS; SEMICONDUCTOR DEVICES; THEIR PREPARATION OR CHEMICAL WORKING-UP

PURPOSE:To obtain a photopolymerizable compsn. having high sensitivity to the visible light by incorporating a combination of a specified aromatic amino compd. and an isoalloxazine type compd. as a photopolymerization initiator in a high-boiling additionally polymerizable compd. CONSTITUTION:An intended photopolymerizable compsn. is obtained by mixing (A) a additionally polymerizable compd. having >=100 deg.C b.p. at normal pressure, such as diethyleneglycol diacrylate or divinyl phthalate with (B) an aromatic amino compd. represented by formula I (R1, R2 are each 1-3C alkyl; X is formyl, carboxy, acyl, or the like; and (n) is 1-3), such as 4-dimethylaminobenzaldehyde or 4-dimethylacetophenone, and (C) a compd. having an isoalloxazine structure represented by formula II (R3, R4 are each H, methyl, or ethyl), such as riboflavin or riboflavin tetrabutyrate.