FLUORINE-CONTAINING POLYMER AND ITS PRODUCTION

PURPOSE:To obtain a fluorine-containing polymer having electro-conductivity, stability against air and resistance to oxidation and being suited as an electronic material, by polymerizing a specified trifluorovinylsilane in the presence of a catalyst which generates active fluorine anions. CONSTITUTI...

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Bibliographic Details
Main Authors NISHIDE KIYOJI, HIYAMA TAMEJIROU
Format Patent
LanguageEnglish
Published 15.12.1984
Subjects
CHEMISTRY
COMPOSITIONS BASED THEREON
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVINGCARBON-TO-CARBON UNSATURATED BONDS
METALLURGY
ORGANIC MACROMOLECULAR COMPOUNDS
THEIR PREPARATION OR CHEMICAL WORKING-UP
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Summary:PURPOSE:To obtain a fluorine-containing polymer having electro-conductivity, stability against air and resistance to oxidation and being suited as an electronic material, by polymerizing a specified trifluorovinylsilane in the presence of a catalyst which generates active fluorine anions. CONSTITUTION:A fluorine-containing polymer represented by formula II (wherein x and n are positive integers, and y is 0 or a positive integer) is obtained by polymerizing a trifluorovinylsilane of formula I (wherein R , R , and R are each a lower alkyl, aryl, or aralkyl), e.g., trifluorovinyltrimethylsilane or trietyltrifluorovinylsilane, in the presence of a catalyst which generates active fluorine anions. Examples of said catalyst include potassium fluoride, tetrabutylammonium fluoride, and tetraoctylphonium fluoride. The obtained polymer has an electric conductivity as high as that of silver bromide.
Bibliography:Application Number: JP19830096906