IONIC NONAQUEOUS LIGAND LIQUID, ITS PRODUCTION, AND USE THEREOF AS CATALYST

• Main Authors: SCHULTE MARCUS, BAHRMANN HELMUT DR
• Format: Patent
• Language: English
• Published: 14.09.1999
• Edition: 6
• Subjects: ACYCLIC OR CARBOCYCLIC COMPOUNDS; ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAININGELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN,SULFUR, SELENIUM OR TELLURIUM; CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOIDCHEMISTRY; CHEMISTRY; HETEROCYCLIC COMPOUNDS; METALLURGY; ORGANIC CHEMISTRY; PERFORMING OPERATIONS; PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL; THEIR RELEVANT APPARATUS; TRANSPORTING

PROBLEM TO BE SOLVED: To produce an ionic nonaqueous liquid suitable for producing a catalyst and immisible with an organic phase by reacting a solution of a specific amine, etc., with an acid, etc., in the presence of an alkali (or alkaline earth) metal salt of a triarylphosphine, etc. SOLUTION: A solution of an amine and/or a phosphine derived from Q<+> (Q<+> is a quaternary ammonium cation or the like) is reacted with an acid and/or an alkylating agent in the presence of an alkali(ne earth) metal salt represented by a triarylphosphineA [A is represented by the formula (Ar to Ar are each a 6-14C aryl; Y1 to Y3 are each a 1-4C alkyl or the like; m1 to m are each 0-5; n to n3 are each 0-3; at least one of n1 to n3 is >=1) ; (a) is same as (n1 +n2 +n13 ) to afford the objective nonaqueous ligand liquid represented by the formula (Q<+> )a A .