PRODUCTION OF URETHANIZED POLYSILOXANE
PROBLEM TO BE SOLVED: To obtain a urethanized polysiloxane having excellent heat resistance by reacting a silanol-group-containing polysiloxane with a cyclic silane compound represented by a specified formula, a polyisocyanate compound and a compound represented by a specified formula. SOLUTION: A s...
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Format | Patent |
Language | English |
Published |
24.06.1997
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Edition | 6 |
Subjects | |
Online Access | Get full text |
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Abstract | PROBLEM TO BE SOLVED: To obtain a urethanized polysiloxane having excellent heat resistance by reacting a silanol-group-containing polysiloxane with a cyclic silane compound represented by a specified formula, a polyisocyanate compound and a compound represented by a specified formula. SOLUTION: A silanol-group-containing polysiloxane (e.g. polydimethylsilicone) is dissolved in e.g. toluene, and about 0.1-5mol, per g of the silanol groups, of a cyclic silane compound (e.g. 1,1-dimethyl-1-sila-2-oxacyclohexane) represented by formula I (wherein R and R are each H, a halogen or the like; and R is a bivalent organic group) is mixed with the solution under heating. Next, a polyisocyanate compound (e.g. tolylene diisocyanate) and an organotin catalyst are added to the mixture, and the resultant mixture is heated. About 0.5-20mol, per equivalent of the isocyanate groups, of a compound (e.g. 2-hydroxyethyl acrylate) represented by formula II (whereon Y is hydroxyl, amino or the like; R is a bivalent organic group; R is H or an alkyl) is added to the mixture, and the entire mixture is reacted under heating to obtain a urethanized polysiloxane. |
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AbstractList | PROBLEM TO BE SOLVED: To obtain a urethanized polysiloxane having excellent heat resistance by reacting a silanol-group-containing polysiloxane with a cyclic silane compound represented by a specified formula, a polyisocyanate compound and a compound represented by a specified formula. SOLUTION: A silanol-group-containing polysiloxane (e.g. polydimethylsilicone) is dissolved in e.g. toluene, and about 0.1-5mol, per g of the silanol groups, of a cyclic silane compound (e.g. 1,1-dimethyl-1-sila-2-oxacyclohexane) represented by formula I (wherein R and R are each H, a halogen or the like; and R is a bivalent organic group) is mixed with the solution under heating. Next, a polyisocyanate compound (e.g. tolylene diisocyanate) and an organotin catalyst are added to the mixture, and the resultant mixture is heated. About 0.5-20mol, per equivalent of the isocyanate groups, of a compound (e.g. 2-hydroxyethyl acrylate) represented by formula II (whereon Y is hydroxyl, amino or the like; R is a bivalent organic group; R is H or an alkyl) is added to the mixture, and the entire mixture is reacted under heating to obtain a urethanized polysiloxane. |
Author | OKAMURA MOMOKO NAGATA MASAKI ERIYAMA YUUICHI |
Author_xml | – fullname: ERIYAMA YUUICHI – fullname: OKAMURA MOMOKO – fullname: NAGATA MASAKI |
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Snippet | PROBLEM TO BE SOLVED: To obtain a urethanized polysiloxane having excellent heat resistance by reacting a silanol-group-containing polysiloxane with a cyclic... |
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SubjectTerms | CHEMISTRY COMPOSITIONS BASED THEREON MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONSONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS METALLURGY ORGANIC MACROMOLECULAR COMPOUNDS THEIR PREPARATION OR CHEMICAL WORKING-UP |
Title | PRODUCTION OF URETHANIZED POLYSILOXANE |
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