PRODUCTION OF TETRACYCLODODECENE DERIVATIVE

PURPOSE:To obtain a tetracyclododecene derivative in high conversion and selectivlty by continuously supplying a (di)cyclopentadiene compound, an olefin compound and an intermediate product to a piston-flow reactor and subjecting the components to thermal addition reaction. CONSTITUTION:This tetracy...

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Bibliographic Details
Main Authors OKA HITOSHI, NAKASE YOSHIHISA, IIO AKIRA
Format Patent
LanguageEnglish
Published 03.10.1995
Edition6
Subjects
ACYCLIC OR CARBOCYCLIC COMPOUNDS
APPARATUS THEREFOR
CHEMISTRY
GENERAL METHODS OF ORGANIC CHEMISTRY
METALLURGY
ORGANIC CHEMISTRY
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Summary:PURPOSE:To obtain a tetracyclododecene derivative in high conversion and selectivlty by continuously supplying a (di)cyclopentadiene compound, an olefin compound and an intermediate product to a piston-flow reactor and subjecting the components to thermal addition reaction. CONSTITUTION:This tetracyclododecene derivative of formula III can be produced by reacting a cyclopentadiene compound and/or a dicyclopentadiene compound with an olefin compound of formula l (R to R each is H, a 1-10C hydrocarbon residue, a halogen or a univalent organic group ; R and R or R and R may together form a bivalent hydrocarbon group or a ring) and a compound of formula II. The reaction is carried out by continuously supplying the reaction raw materials to a piston-flow reactor and subjecting the materials to Diels-Alder type thermal addition reaction at 80-200 deg.C. The compound of formula III is useful as a raw material for transparent resins and resins for optical use.
Bibliography:Application Number: JP19940068196